Astrologer priority is as follows from the folks I've been talking with on our server:
Spellspeed (until 700-800) > Determination > Piety | Crit
Simply put Astros when played correctly have huge mana pools and greatly benefit from faster casts while doing hard raid content. As you approach 2.2 casting speed you can start doing super slick sliding casts for small mechanic shifts, and otherwise cut corners that you would otherwise be hard pressed to manage. Determination after should be obvious as you want your overall heals more effective. Crit is just terrible on Astros IMO. I could MAYBE see shield based astros putting a different priority on critical stats... but Whitemage/Astro is MEH in raid content (I've run it a notable amount). Personally I'd rather pick up the the extra Piety over crit as mana does get tight if you have to resurrect a person here or there. Or if you have to bounce someone back from a sloppy mechanic.