Should use it when you got hate, you understand your Cool downs (Most Drk's don't.), there are 3 mobs or less (or about to be) as single target DPS starts to edge out over AoE. Any boss if your healer isn't trash and you understand the Cool down rotation for the fight, as you shouldn't be tanking with grit up once you've got a solid hate lead.
The above is assuming your armor is up to date along with your healer's. If either is behind, I'd test the waters first to make sure you won't go face planting into the ground.

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