I remember at launch I was making Copper Nugs and selling them for 2k a pop all day long by the Blacksmith NPC. There's certainly going to be big initial opportunity on the new servers.
As for mats, gear, etc, I don't think it will be a huge problem. People who really want to cash in will have craft jobs to 50 in a matter of days, and they won't have to deal with figuring out recipes or where mats drop from.

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