When I was leveling SCH in steel vigil (first healer class I've actually played that high), I was in a group and I thought I was doing ok, but I kept running low in MP. I had no idea why or if that was just what I was supposed to expect. I was managing with lucid dreaming and energy drain (I think???), but just barely. Then one of the DPS asks me if I'm using Ruin II most of the time, which I was for the instant cast. He kindly points out the MP difference btwn that and Ruin I, which I had overlooked b/c I'm a noob to the job. I switched to using Ruin II only when I needed to move and made Ruin I primary: no more MP management issue.
He just started with a simple question about what what ability I was using, and yeah I tensed up a bit when he first asked cus you can't hear tone in text and the question's phrasing could have been either a genuine interrogative or a setup to tell me I wasn't DPSing enough or something, and I didn't know which way it would fall. But I'm not an idiot and chose to answer civilly, and then I got a much appreciated bit of correction.
My point here is maybe, if you think someone is missing or misusing something in their skillset, I'd say just ask them about it. Maybe with "Genuine question" at the start or end, to keep them from misreading your question as accusatory when its not intended to be. I wouldn't just start with telling them how to do better, though. Asking a question first treats them like they're people who have brains and are capable of understanding concepts, which can only be helpful for you. It also lets them express their case for why they do a thing a way they do a thing if they wish. Being told at just annoys people b/c they have not even agreed to your authority and to learning anything from you, yet.
All that said, I generally don't care about how others play as long as we are actually clearing the content. But when I do run into unexpected wipes, I ask questions and try to examine what's gone wrong, so the above idea still holds, I guess.