It'll work even better later in the game. WHM+MNK is one of the most powerful duo combinations in the game. MNK has one of the highest damage outputs while maintaining reasonable survivability, and WHM is a powerhouse when it comes to curing.
The only problem is that it may get a bit boring for the WHM, as her job will get pretty repetitive and just consist of spamming cures and occasionally erase and such stuff. But if she gets bored she can always start to melee, which isn't a bad thing in most situations (only on AoE high damaging or debuffing mobs).


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