Sounds like one PS3 version per SE account, since it's limited to having one game per PSN account.
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It's good that you brought this up, as this happened to me when I preordered the 1.0 CE from SE. Unfortunately, SE cannot control UPS delivery times (which is the shipment they used with me), and I ended up getting my CE at around 7pm on the day of early access launch lol. You'll get it the same day for sure, but morning or evening is completely up to the delivery people, not SE.
I'll be preordering mine from a local shop if I can help it.
I'm really wondering the same thing. I'd like to get the PS3 version so that I can play on whichever system I want (PS3 when family are using my PC for example), but I'd want to apply the pre-order code to my old account and have my old account the one I use on PS3 anyway.
I have a question regarding the Standard to Collector edition upgrade option, will this count also as a pre-order?
Which means, if we already own Standard and decide to upgrade to Collectors before December 31, 2013, will we also receive the Pre-Order bonus items?
I also found a small error on the In-Game Items section (http://na.finalfantasyxiv.com/product/index.html), once you click More Info to read about every item, For the Coeurl Mount and Behemoth Barding, it looks like the red font information for each of them is changed around.
The Coeurl Mount should be the one saying "* Players will be able to ride mounts once they have reached level 20 and have obtained a chocobo."
And for the Behemoth Barding should say "* Players must first reach level 20 to obtain a chocobo before they can outfit it with barding."
Guess I am lucky there. All my deliveries from UPS arrive by 10:45AM. The reason I asked this question is the fact that SE ships their products via UPS Ground. I am sure that they are well aware of the shipping schedules for various sections of the country. I just wanted to make sure that they were going to take that into account when scheduling. I have had the original PS3 version backordered on Amazon since 10 Aug 2010. If they update their information by Tuesday or Wednsday of next week I will upgrade to the CE there and know I will get it on time. If they don't I will pre-order through SE to make sure I get all the benefits from buying the CE.