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Will I be able to play the Windows version and the PlayStation 3 version with a single service account?
Yes, you can play the Windows version and the PlayStation 3 version with the same service account. However, you will need to purchase a copy of both versions and register the registration codes accordingly.
* Please note that you cannot play both versions simultaneously if you register both products under the same service account. If you wish to play simultaneously, please be sure to register them under different service accounts.