I recommend using http://wiki.ffxiclopedia.org/wiki/Category:Missions and get yourself through the main scenario (at least rank 6), and then start working your way through at the very least, Rise of the Zilart.
From there you've got a ton of options available, and access to some relevant end game content (Dynamis).
If you're a storyline purist, and want to experience things in the order they were released, go through:
Chains of Promathia (unlocks more Dynamis areas, Limbus)
Aht Urhgan (unlocks Assaults, Salvage, Einerjar and some other things)
and at least part of the way through Wings of the Goddess (Cait Sith Mission) (unlocks Campaign, Walk of Echoes, portions of Voidwatch)
Abyssea (good place to xp 75+, still has some relevant gear worth getting)
Seekers of Adoulin (unlocks Skirmish, Delve, Wildskeeper Rieves, access to most modern gear)
But my best recommendation, is to enjoy FFXI at your own pace, don't feel rushed to get to end game. Even though it's an old game, it's still a very beautifully crafted game with great characters, music, stories and solid gameplay. Try to find a nice social linkshell who doesn't mind you asking occasional questions or help. You'll learn a lot from them about what you can think about doing to get access to join them for other events.

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