The full physical collector's edition for pc won't work but getting it for ps3 will. Plus you will be given another free 30 day trial. Items are linked to your SE account and can be redeemed once you enter the code in the psn store.

If you own a ps3 this will be very easy. If you do not own the console you will need to go to the PlayStation website and set up an account. Then go to the SE website and link the two. When you get your codes you can redeem them directly from the psn store which you can access from their website.