In Endwalker we got so far following Sets / Items

Northsea Coat = Unisex
Sophist's Set = Unisex
Gaja Set = Unisex
Omega-M Set
Omega-F Set
Silver Tora Kabuto
Golden Tora Kabuto
Little Lady's Crown
Clown's Set = Unisex
Happiness Set = Unisex
Wayfarer's Set = Unisex
Varsity Set = first Set with a Skirt
Appointed Set = Unisex (more Male)
Street Attire Set = Unisex (to Modern)
Summer Sunset = Female & Male Version
Isle Farmhand's Widebottoms = Unisex
Isle Farmhand's Set = Unisex (to Modern)
Isle Explorer's Set = Unisex
Lawless Enforcer = Male even if it's Unisex
Fat Cat = Unisex
Wake Doctor Set = Male even if it's Unisex
Noir Set = Male even if it's Unisex
Far Northern Set = Unisex
Gaia's Set = Ultra ugly
Yakaku Set = has this ugly top with one arm hanging around like you either lost 1 arm or were too stupid to dress properly
Isle Shepherd's Set = Unisex
Leafman Head
Isle Vacationer's Set = The Only Female Part in this is the Tie-front Shirt, Shirt & Tanga - the rest is Unisex
Salon Server's Set = The Only Female Part in this is the Salon Server's Dress Vest & Salon Server's Skirt - the rest is Unisex
Valentione Emissary's Dress Set = Female set with an ugly clipping Skirt
Valentione Emissary's Set = Unisex
Educand's Set = Unisex with 2 Female Parts - Sailor Top (could be even unisex) and the Sailor Skirt
Tonberry Set = Unisex
Baronial Set = Unisex (more Male)
Island Resort Set = Unisex
Pajama Sets (Plain, Chocobo & Cactuar) = all Unisex
Seigneur's Set = Unisex (more Male)
Shishu Set = Unisex
Phoenix Riser Set = ultra Ugly Unisex
Magitek Set = ultra Ugly Unisex
Iceheart Set = ugly Female Set which we had already in Game for Free
Tactical A-1, A-2, B-1, B-2, C-1, C-2 = Unisex and not a single Female Part in these 6 Sets
Fierce Tyrant's Set = Male
Recreationisle Set = even if it's Unisex the look is full Male
Gleaner's Set = Unisex
Island Leaf
Felicitous Set = Unisex
Minmisle
Martial Artist's Set = Unisex

Most of the Unisex Glamours tend more to Male as to Female Items.