Edited in case some of this is spoilers.
I have two Raen in my adventurer squadron and know you can have more, as well as Xaela. You can pretty much come up with any story you like for the reasons they're there (beyond the generic standard given). There's a Raen involved with mining quests in Idyllshire. Kurenai's Custom Deliveries will open some information on Sui-no-Sato, but I won't spoil further in case some of you haven't done that yet. Suffice it to say, I would expect more Raen to emerge over time.
There is a Raen based in Namai for a carpentry commission in CRP 60-70.
There are Xaela involved in another set of Custom Deliveries, and some are indeed involved in the Doman Restoration. Xaela will also be part of the Namazu beast tribe quests, but as they take place on the Azim Steppe, that's an obvious one. And I'm sure no one's forgotten Sidurgu, lurking in Ishgard (unless he moves after you do DRK stuff. I haven't really done DRK stuff).