Yeah, proc are important. In MCH for ex, when I'm trying the O4S dummy, I've done it one time 30s remaining and the other times that was around 20s, just because I've a good RNG.
My answer about the OP's question is: most challenging and wanted is different a lot. NIN is not particulary hard except for timing TA, but is surely the most wanted job because of that. MCH is way the hardest dps imo, in all point, but because he had Hypercharge, it is at the same levelo of the NIN for "wanted job".