I believe a few things so far about SMN gear.

1. Left side is basically locked in regardless of any ACC cap you're trying to reach in 3.05 as gear stands; the ACC SS pieces are undeniably the worst left side pieces since the alternative is always more attractive and you get enough ACC anyway. Gordian hat, belt, boots. Tome chest, gloves, legs. Right side is almost as locked in, it's gonna be Gordian ring and wrist, tome ring. Everything else is probably tome.

2. CHR > DET > SS per the content so far. The whole point of SMN over BLM in the current system is that AoE/multi advantage, and content allows for it generously so far fortunately for us. For AS2 it's more like CHR >>>>>> DET >>>> SS. Weapon would be Gordian for all current content except maybe A4S where that theoretical SS > DET thing could come into place if true.

Following those two rules, I've made 3 ACC caps (well, basically just because the game locks in the left side so heavily and gives you so much ACC).

- Content below A3S ACC: http://ffxiv.ariyala.com/RDPL
- A3S ACC: http://ffxiv.ariyala.com/RDPM
- A4S ACC: http://ffxiv.ariyala.com/RDPN