I asked, but the short answer was simply "no". Because of the disjointed departments and processes, it seems that no one has the power (or knows who would) to do such a thing.

The issue is still not actually resolved. I went to buy the game via the Playstation Store and the buy button is missing. It won't let me purchase because apparently I already own it when I registered the hard copy I purchased for service account #1. Looks like my only option is to purchase another hard copy for the PS3... Which I'm extremely hesitant to do at this point. With my luck, that won't work either. :/