From what I remember, you need to complete a quest first given by the levemete in the Adventurer's Guild of your starting nation (if you started as MRD that would mean it would be the Limsa Lominsa one) before you can do levequests (when you did the level 10 story quest for your starting nation the proprietor of the Adventurer's Guild would have mentioned this person wants to speak to you). This person will send you to speak to a levemete in a specific camp, who will then issue you a trial levequest. Completing this leve will complete this quest also, and then unlock levequests completely.

It's rather convoluted I know, but hopefully this has helped.