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There are 24 available slots for saving your characters various roles however by my count there are potentially 29 roles you could conceivably have your character using if they attempt to do everything DoH and DoL included.
I know this may be a bit of a niche, completist problem but is there any way you can increase the number of available slots so that the various armoury items get allocated?
Which leads me on to a second question, can you increase the number of slots in your armoury?
If you unlock every single class/job, you should have 45 gearsets available for your character, which should be more than enough to cover everything you need and then some. An increase in the Armoury Chest would be nice though, the Main Arm tab alone is definitely in need of a boost, for other gear you can try using the Glamour Dresser which has 400 slots.
When you first unlock the ability to save gear sets, you start off with something like 6 or 8 gear set slots. (I don't remember the exact number, but it's around there.) You only have one class at that point, since this happens at the conclusion of your first level 10 class quest, which also unlocks the ability to do the unlock quests for additional classes. So those 6 or 8 or so slots include a few extras.
After that, each class or job you unlock adds one more gear set slot. The ARR combat jobs, involving first unlocking a class and later unlocking its associated job, add a gear set slot for each. Since you won't need the base class anymore after that upgrade, those give you some extras as well.
You'll end up having as many gear set slots as the number of jobs you play, plus the number of ARR combat classes you've unlocked and later grown out of, plus those few extras you started off with way back at level 10.
As for the armory chest itself, I wish we could get more space there. The weapon section doesn't hold enough if you're working on relics so have multiple weapons per combat job, and the ring section doesn't hold enough if your jobs are too spread out in levels to share jewelry.