Turbo Controller would be the only correct answer.
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I've loaded up other games while waiting between behests. Only one that has managed to cause FFXIV to throw up a error was Vanguard. Funny enough I was running both games in windowed mode. Though I'm more than willing to blame the other games incredibly poor engine.
Yeah, the whole DX crash has always been a ridiculous issue with the game engine. Fortunately this will problem will be gone in 2.0, as per Yoshi.