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I use it at the start of the fight, and then whenever the group is gathered together.
Such as on fights like Alexander 4, I put Eos/Selene in the middle of the room, and Deployment Tactics on her. So the spread hits everyone even though I'm far from those groups of people.
Using Deployment Tactics on your fairy when shes close to melee/tanks is an awesome way to get that cover in without needing to run in and succor o/
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Ravana EX during adds, and before swift liberation are textbook uses for the skill. Alexander 4 where DPS has to handle adds is perfect as well. I always E4E and Adlo Selene and pass it off to the party that way since we control where our faries are placed!
Very rarely will I hit the tank with the adlo/E4E for deployment unless I want to pass it to just the OT next to them as well.